Gasoil removal from aqueous solution using magnetic metal-organic framework adsorbent based on the cellulosic fibrous of Prosopis farcta plant

Abstract

Recently, the leakage of Gasoil and other petroleum substances into the seas, surface water, and wastewater has become a global problem; therefore, providing a solution to remove these pollutants seems vital. In the current research, we investigated the removal of floating Gasoil from aqueous solutions. First, the magnetic metal-organic framework was prepared as a new adsorbent based on the cellulosic fibrous of the Prosopis farcta plant (magnetic- cellulose@MIL-53(Fe) carbon aerogel). Using design of experiment, the effect of parameters pH, Gasoil concentration, and adsorbent weight on Gasoil removal were investigated. The adsorbent prepared under optimal parameters can remove 100% floating Gasoil from the aqueous solution. The adsorption capacity of the magnetic- cellulose@MIL-53 (Fe) carbon aerogel is 7.48 g.g−1, which is almost 100 times more than other Fe-based adsorbents. The study of the effect of time showed that the adsorption of Gasoil by the adsorbent is not dependent on time. Gasoil adsorption on magnetic- cellulose@MIL-53(Fe) carbon aerogel follows the Freundlich isotherm with a correlation coefficient of 0.9933. Thermodynamic factors Gibbs free energy, enthalpy, and entropy changes have been calculated. Accordingly, magnetic- cellulose @MIL-53(Fe) carbon aerogel has rapid separation and high stability, and it could be used as a good adsorbent to remove Gasoil from an aqueous solution. With good cycling stability of 86% retention of the initial adsorption value after ten adsorption/desorption cycles.