Meta-Phenylenediamine-Derived Silver-Containing Nanoporous Hyper-Cross-Linked Polymer: An Innovative Fluorescence Probe for S2O32− ion Detection in Aqueous Media

Abstract

The meta-phenylenediamine polymer, when hyper-cross-linked, exhibits a minimal fluorescence intensity. However, the introduction of silver ions induces a significant increase in intensity, attributed to the plasmonic effect. This heightened intensity is selectively increased more upon the addition of thiosulfate ions. Capitalizing on this property, a fluorescence probe was developed. The correlation between fluorescence intensity reduction and S2O32− concentration follows a linear and consistent pattern. The precursor’s response to diverse anions such as SO42−, CO32−, HPO42−, Cr2O72−, F−, Cl−, Br−, I−, H2PO4−, CH3COO−, NO3−, ClO−, and HCO3− was also examined. Under optimal conditions, the probe exhibited a linear range of 0.5-3 μM with a detection limit of 0.01 μM. Its effectiveness was demonstrated in measuring thiosulfate concentrations in aqueous media.