Authors | حسین نعیمی,محسن مرادیان |
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Journal | TETRAHEDRON-ASYMMETR |
Page number | 429 |
Volume number | 25 |
IF | 2.155 |
Paper Type | Full Paper |
Published At | 2014-03-11 |
Journal Grade | Scientific - research |
Journal Type | Electronic |
Journal Country | Iran, Islamic Republic Of |
Journal Index | ISI ,SCOPUS ,PubMed |
Abstract
A novel thiosalen ligand based on a thioether has been prepared and readily coordinated with copper(I) salts (CuCl, CuBr, CuI, and CuCN). The new organometallic catalyst was used for the direct and enantioselective alkynylations of imines in an A3-coupling reaction. In this reaction, the corresponding propargylamines were obtained as single products in excellent yields and with good enantioselectivities.
tags: Thioether, Schiff base, A3-coupling