Synthesis of Nanocrystalline CeO2 with High Surface Area by the Taguchi Method and its Application in Methanation

نویسندگانبهزاد نعمت الهی-مهران رضائی-ابراهیم نعمتی لای
نشریهChemical Engineering & Technology
شماره صفحات265 تا 273
نوع مقالهFull Paper
تاریخ انتشار12 December 2014
رتبه نشریهISI
نوع نشریهچاپی
کشور محل چاپآلمان
نمایه نشریهISI ,SCOPUS

چکیده مقاله

Mesoporous nanocrystalline cerium(IV) oxide (CeO2) with high surface area was synthesized by precipitation using a cationic surfactant and employed as support for a nickel catalyst in CO methanation. The preparation factors of CeO2 were optimized by the Taguchi method to achieve a sample with high surface area. The obtained results reveal that the sample prepared under optimized conditions has a mesoporous structure with high surface area and crystallite size. The addition of a surfactant significantly influences the structural properties of CeO2 and improves the specific surface area. The optimized sample was employed as support for a nickel catalyst in CO methanation reaction. The prepared catalyst possessed a high activity compared to a commercial methanation catalyst.