Performance Study on Microchannel Coated Catalytic Plate Reactor Using Electrophoresis Technique for Medium Temperature Shift (MTS) Reaction

Abstract

The medium temperature shift (MTS) microreactor has been proposed in order to decrease the CO content of reformate for fuel cell applications. The Ni–K/CeO₂ catalyst is synthesized and coated on stainless-steel plates by electrophoretic deposition (EPD) and then evaluated at 300–390 °C. The morphology of the catalyst layers are analyzed by X-ray diffractometry (XRD), scanning electron microscopy (SEM), and three-dimensional (3D) optical microscopy. The FT-IR analysis and conductivity measurements are used for slurry characteristics of different polyethylenimine (PEI) contents. The activity of the catalytic plates inside the microreactor is tested at different gas hourly space velocity (GHSV) values and H₂O/CO molar ratio of 3. The CO conversion is raised by increasing the coating time from 1 min to 3 min, and it has an optimum at 140 V for applied voltage (between 30 V and 180 V). Also, it is found that the …