Exploring the effect of Co concentration on magnetic hyperthermia properties of CoxFe3-xO4 nanoparticles

AuthorsAhmad Reza Yasemian, Mohammad Almasi Kashi, Abdolali Ramazani
JournalMaterials Research Express
Presented byدانشگاه کاشان
Paper TypeFull Paper
Published At2020/1/10
Journal GradeISI
Journal TypeTypographic
Journal CountryUnited Kingdom

Abstract

Although enhanced ferrite nanoparticles (NPs) have been envisioned for use in future biomedical applications, less attempt has been made to tailoring and optimizing their detailed magnetic properties and specific loss power (SLP) values. Herein, Co x Fe 3-x O 4 (0≤ x≤ 1) NPs are synthesized using a co-precipitation method at 80 C in the presence of air atmosphere. The effect of varying Co concentration on crystalline, morphological, magnetic and hyperthermia properties is also investigated in detail. Hysteresis loop measurements showed an increase in coercivity (H c) from 7.75 to 340.50 Oe, and a decrease in saturation magnetization (M s) from 59.10 to 32.70 emu/g with increasing x= 0 (pure magnetite) to x= 1 (pure Co ferrite), respectively. In addition to confirming the hysteresis loop results, first-order reversal curve (FORC) analysis estimated a 52% decrease in superparamagnetic (SP) fraction …