ارائه شده در همایش‌ها

Authors

M. Fatehi, M. Barati

Conference Title

International Congress of Sciences and Innovative Technologies

Holding Date of Conference

2018

Page number

95

Conference Type

SPEECH

Conference Level

International Conferences

Abstract

Sesame oil was treated to produce fatty acid methyl esters (FAMEs) in supercritical methanol medium in presence of CaO and MgO catalysts supported on γ-Al₂O₃. Reaction was performed in a 50mL stainless steel micro-reactor at 300^oC and 80 MPa. Catalysts were characterized using XRD, ICP and SEM techniques. Liquid products were analyzed using GC-MS and CaO/Al₂O₃ showed higher FAME production yield than MgO/Al₂O₃. Alkanes and aromatics are byproducts of reaction. The produced FAMEs were completely unsaturated ones that can be demonstrated that hydrogen gas production in the medium. Results showed that 63%wt and 86%wt of triglycerides were converted to methyl esters in presence of MgO/Al₂O₃ and CaO/Al₂O₃, respectively.

Authors

M Barati, G Kahid

Conference Title

19th Iranian Congress of Chemistry

Holding Date of Conference

2017-2-20

Event Place

Shiraz

Conference Type

IN SERIES

Conference Level

National Conferences

Abstract

Conversion of Iranian bagasse to gaseous and liquid fuels was carried out in a basic and reducing medium of subcritical water and supercritical methanol with 80%wt and 20%wt, respectively.The process was performed in a bomb 200 mL reactor in presence of Cu /γAl -MgO catalysts. The catalysts were promoted with different percentages of K and the effects of Cu and Kloadings on quality and quantity of biofuel products were investigated. The catalysts wereprepared with 20wt% of Cu and 1, 2.5, 5, 7.5 and 10wt% of K. They were shown in the text withCu20, Cu20-K1, Cu20-K2.5, Cu20-K5, Cu20-K7 and Cu20-K10, respectively. 3