Novel room temperature synthesis of ZnO nanosheets, characterization and potentials in light harvesting applications and electrochemical devices

چکیده مقاله

Zinc oxide nanosheets (ZnONSs) were successfully synthesized using Zn(NO3)2·4H2O as the starting reagent in ammonia atmosphere at roomtemperature by a novel gas-solution precipitationmethod. XRD and EDS patterns indicated that pure ZnONSs were produced only in 15min reaction time. Besides, investigating the optical prop- erties of the as-prepared ZnO nanosheets using UV–Vis diffused reflectance spectroscopy (DRS) exhibited their semiconducting property by revealing one optical band gap in 3.3 eV. Moreover, rhodamine B and methylene blue degradation were used as a probe reaction to test the as-synthesized ZnONSs photoactivity. Furthermore, a possible reaction mechanism for ZnONSs formation was discussed. On the other hand, operation of ZnONSs in Dye-sensitized solar cell (DSSC) was investigated by current density-voltage (Jsc-Voc) curve. Finally, a pencil graphite electrode was decorated using ZnONSs and pure MWCNT to provide an electrochemical device for Pb+2 ions sensing. This modified electrode showed agreeable responses to trace amounts of Pb+2 in NaOAC/ HOAC buffer solutions. The limit of detection was found to be 0.112 nmol L−1 for Pb+2.