The effect of promoters on the CO۲ reforming activity and coke formation of nanocrystalline Ni/Al۲O۳ catalysts prepared by microemulsion method

چکیده مقاله

Mesoporous nanocrystalline nickel-alumina promoted catalysts with high surface area were prepared by microemulsion (ME) method and employed in dry reforming of methane reaction. The catalysts were characterized by X-ray diffraction (XRD), Brunauer-Emmett-Teller surface area analysis (BET), temperature programmed reduction (TPR) and temperature programmed oxidation (TPO) techniques. The results showed that the prepared catalysts had high porosity with great surface area and small crystallite size. Among the K2O, MgO, CaO and BaO promoters, the MgO promoter showed considerable effect on catalytic performance and coke suppression of catalyst.