The effectofgrowthrateenhancementonthemagneticpropertiesand microstructuresofacelectrodepositedConanowiresusingnon-symmetric reductive/oxidativevoltage

نویسندگانمحمد الماسی کاشی-عبد العلی رمضانی-مریم غفاری-وحیده بیضی اصفهانی
نشریهJ CRYST GROWTH
ارائه به نام دانشگاهدانشگاه کاشان
نوع مقالهFull Paper
تاریخ انتشار2009-8-01
رتبه نشریهISI
نوع نشریهچاپی
کشور محل چاپآروبا
نمایه نشریهISI ,SCOPUS

چکیده مقاله

Non-symmetricreductive/oxidativevoltagewasemployedtoelectrodeposittheConanowiresthrough the aluminabarrierlayerintoporousaluminumoxidetemplatesgrowninoxalicacid.Theminimum and maximumoxidativevoltageswere12and18Vwhilethemaximumdifferencebetweenthe oxidativeandreductivevoltagewas6V.Theeffectofbarrierlayermodificationonthegrowthrateof the Conanowiresduringtheelectrodepositionprocedurewasstudied.Inordertoinvestigatetheeffects of thenon-symmetricelectrodepositionvoltageonthegrowthratethewire’slength,thesaturation magnetization,theinstantaneousandthermscurrentweremeasured.Differentreductive/oxidative voltagesenableustofabricateelectrodepositednanowireswithawidevarietyofgrowthrates.Using same reductivevoltage,reducingtheoxidativevoltageincreasedthegrowthrate.Atthesamereductive voltage(18V),averagegrowthratewasseentoincrease2.5times,whentheoxidativevoltagereduces to 12Vfrominitially18V.Thebarrierlayerthicknessofthesamplesmadewithdifferentnon- symmetricreductive/oxidativedepositionvoltagewasinvestigatedthroughimpedancemeasurement during thedepositionprocedure.Reducingthegrowthrateofdepositionreducestheintensityofthe (100)preferentialdirectionofhcpphasetherebyimprovingthemagneticproperties.Manipulatingthe growthratethroughnon-symmetricelectrodepositionenablesustofabricatetheConanowireswith coercivity rangingfrom460to1850Oe.