Electrodeposited metal nanowires as transparent conductive electrodes: Their release conditions, electrical conductivity, optical transparency and chemical stability

چکیده مقاله

Metal nanowires (MNWs) have gained considerable attention from research groups as they can be
effectively applied in new transparent conductive electrodes (TCEs), replacing indium tin oxide (ITO)
materials. However, using conventional synthetic methods including the chemical solution, Ag and Cu
NW-based TCEs have been found to be non-uniform and unstable in reactive environments. Here, we
present an innovative high-throughput method in the fabrication of Ni, AgNi, AgCu and AgNiCu NWbased
TCEs using the electrodeposition of metal ions into anodic aluminum oxide (AAO) templates,
followed by drop-coating of highly uniform MNWs on glass substrates. After the complete release of
60 μm long MNWs with high crystallinity from the templates, the resulting TCEs show enhanced
electrical, optical and chemical stability properties compared to those of ITOs and Ag NW-based
TCEs. Notably, in the case of Ag98Ni1Cu1 NW-based TCEs, we obtain a low sheet resistance of 40 Ω
sq-1 together with a high transparency of 90%, thereby evidencing the fabrication of high-quality TCEs
without byproducts and difficult post-treatments. These MNW-based TCEs are also exposed to
sulfurization environment, showing chemical stability with no precedent in the literature