Grinding-assisted synthesis of heterocyclic fullerene derivatives under solvent-free conditions

چکیده مقاله

In this research, a green, easy and effective solvent-free procedure for the synthesis of heterocyclic fullerene derivatives has been achieved via 1,3-dipolar cycloaddition reaction of C60, substituted arylhydrazones/oximes, and PhI(OAc)2 under grinding as a simple physical-mechanical method. This approach does not involve any hazardous organic solvent and has various advantages including design of safe reaction conditions, good to moderate yields and short reaction times.