Magnetic nanoscaled core–shell structured Fe۳O۴@L-proline: An efficient, reusable and eco-friendly nanocatalyst for diastereoselective synthesis of fulleropyrrolidines

چکیده مقاله

In this study, a novel and general method has been developed for the one-pot diastereoselective synthesis of fulleropyrrolidines from C60, L-proline and acetophenone derivatives using magnetite nanoparticles Fe3O4@SiO2–proline as an efficient magnetic organocatalyst. The prepared catalyst samples were characterized using XRD, VSM, EDS, SEM, FT-IR, and Fe3O4@SiO2–proline showed an excellent catalytic activity for the diastereoselective synthesis of fulleropyrrolidines. Prominent among the advantages of this method are the use of a magnetically recoverable and reusable catalyst, simple work up procedure, unique diastereoselective effectiveness and good to high product yields. The fulleropyrrolidines were calculated using a density functional theory method (DFT) and a trans stereochemistry of the products was established.